INOR 2019 – San Diego Session Locator and Program Sessions (draft)

MONDAY AFTERNOON

Section A

Marriott Marquis San Diego Marina
Marina Ballroom Salon F

ACS Award in Pure Chemistry: Symposium in Honor of Danna Freedman

H. Karunadasa, J. Zadrozny, Organizers, Presiding

1:30 Introductory Remarks.

1:35 292. Lanthanide-based single- molecule magnets with high blocking temperatures. C. Gould, P. Bunting, A. Vincent, S. Demir, K.R. McClain, L. Darago, K. Chakarawet, M. Gonzalez, K.R. Meihaus, J. Zadrozny, M. Nippe, J.D. Rinehart, S. Teat, B.G. Harvey, W.J. Evans, J.R. Long 2:00 293. Control of magnetic relaxation via spin bath design. J. Zadrozny

2:25 294. Halide perovskites under pressure. A. Jaffe, Y. Lin, W. Mao, H. Karunadasa

2:50 295. Developing a mild and modular route to chemically modified electrodes for photoelectrochemical cells. C. Hanna, J.Y. Yang

3:15 Intermission.

3:30 296. Tunable metal oxide materials via assembly of [NaP5W30O110]14− . A.M. Schimpf

3:55 297. Making flexible, transparent electronic devices a reality: Organic polymers, heterojunctions, oxides and beyond. T.J. Marks

4:20 298. On the selectivity of the reduction of CO2 on gold electrodes. D.G. Nocera

4:45 Concluding Remarks.

Section B

Marriott Marquis San Diego Marina
Marriott Grand Ballroom

Section 9 Learning from Nature: Earth- Abundant Metals for Oxidation Catalysis

S. S. David, T. A. Jackson, Organizers
A. Mukherjee, Organizer, Presiding

1:30 299. New insights into oxidation catalysis with copper. M.T. Kieber-Emmons, D. Ramirez, P. VanNatta, G. Ali, A. Velarde

1:55 300. Geometric and electronic structure contributions to reactivity of Mn–oxygen intermediates. T.A. Jackson, J. Parham, M. Denler

2:20 301. Copper(I)-dioxygen adduct stabilization and substrate oxidative reactivity. K.D. Karlin 2:50 302. Reactivity of an alkyl thiolate-ligated FeIII-superoxo intermediate derived from dioxygen. J. Kovacs, M.N. Blakely, M.A. Dedushko, P. Poon, A. Downing, D. Rogers, P. Gannon 3:20 Intermission.

3:30 303. Going a step beyond nature: Catalyzing aldehyde deformylation with a non- enzymatic metal. C.R. Goldsmith, A.C. Saunders

3:55 304. Intermediates in aromatic hydroxylation catalyzed by a Rieske monooxygenase. M.S. Rogers, J.D. Lipscomb

4:25 305. Differentiating between radical rebound hydroxylation versus H-atom transfer with non- heme iron(III)-hydroxo complexes. A.R. Fout, M.J. Drummond

4:50 306. Site and enantioselective C-H oxidations inspired in nature. M. Milan, M. Scianfanelli, A. Palone, G. Olivo, X. Ribas, M. Bietti, M. Costas

5:20 307. Cu-promoted hydroxylation of sp2 and sp3 C–H bonds: From enzyme modeling to synthetic applications. I. Garcia- Bosch

Section C

Marriott Marquis San Diego Marina
Solana

Inorganic Nanoscience Award Symposium

J. Millstone, Organizer, Presiding

1:30 308. Plasmonic metal oxide nanocrystals. D.J. Milliron 2:15 309. Details of ligands on nanocrystal surfaces. C.J. Murphy

2:45 310. Inverse design of interactions for assembly. T. Truskett

3:15 311. Exploiting interfacial assemblies of nanoparticle surfactants to design reconfigurable materials and devices. B. Helms, W. Feng, J. Forth, T.P. Russell

3:45 Intermission.

4:00 312. Prospects and challenges for unity quantum yield nanocrystal lumophores. P. Alivisatos

4:30 313. Synthesis of multi- component nanocrystals and their application as catalysts to store energy in chemicals. R. Buonsanti

5:00 314. Dopants and defects in colloidal semiconductor nanocrystals. D.R. Gamelin

Section D

Marriott Marquis San Diego Marina
Rancho Santa Fe 2

Inorganic Chemistry for Sustainable Energy & Environment

L. A. Berben, Organizer, Presiding

1:30 315. Selective reduction of CO2 to water by molecular catalysts attached to carbon surfaces. C.P. Kubiak, A. Zhanaidarova

2:00 316. Sustainable and renewable carbon and nitrogen cycles for fuel and crop production. D.G. Nocera

2:30 317. Advances and research challenges in chemical and materials research for renewable energy conversion, storage, and utilization. W. Tumas

3:00 Intermission.

3:20 318. Mechanisms for the activation of supported oxometal complexes for olefin metathesis. S.L. Scott, F. Zhang, L. Li, C. Vandervelden, B. Peters

3:50 319. Conductive metal- organic frameworks for electrocatalytic H2 evolution. S.C. Marinescu

4:20 320. Mechanistic studies of technologically-relevant dye- sensitized and cocatalyst- containing photocatalytic materials. J.M. Cardon, W. Gaieck, K. Tkaczibson, N. Farhang, S. Keene, S. Luo, H. Chen, S. Ardo

4:50 321. Controlling the electrocatalytic reduction of O2 to H2O/H2O2 using nontraditional porphyrinoid scaffolds. Q. Cai, J. Eddy, T. Qiu, J. Rosenthal

Section E

Marriott Marquis San Diego Marina
Santa Rosa

Emerging Research in Molecular Synthesis

A. C. Brewer, V. A. Schmidt, J. Y. Yang, Organizers
J. M. Hoover, Organizer, Presiding
I. Tonks, Presiding

1:30 322. Cross-electrophile coupling to form Csp3-Csp2bonds. D.J. Weix

2:00 323. Cross-coupling with three components and in three dimensions. K.M. Engle

2:30 324. Unraveling the mechanism of catalytic decarboxylative coupling reactions. J.M. Hoover

3:00 Intermission.

3:15 325. Complex molecule synthesis via the enantioselective hydroformylation/hydroacylation/al dol sequence. C.R. Landis

3:45 326. Incorporating aryne chemistry into Ti redox catalytic reactions: Ti-catalyzed synthesis of substituted napthalenes via in situ generated arynes. I. Tonks, B. Reiner

4:15 327. Identifying catalysts and reactor conditions for tailored polymer rheology. S.E. Smith, A. Mohan, G. Kiss, J.M. Soulages

Section F

Marriott Marquis San Diego Marina
Marriott Grand Ballroom Section 8

Surface Chemistry & Structure in Ligand Protected Nanoparticles

C. J. Johnson, Organizer
B. Lear, Organizer, Presiding

1:30 Introductory Remarks.

1:35 328. Atomically precise gold nanoclusters: Surface structure and implications. R. Jin

2:20 329. Atomically-precise nanocluster electronic structure and reactivity from atomically- imprecise syntheses. C.J. Johnson, A. Cirri, H. Morales, C. Kmiotek 2:50 Intermission.

3:00 330. Effects of surface structure on the chirality and luminescence of thiolate- and phosphine-stabilized gold nanoclusters. C.M. Aikens

3:45 331. Chemical control over the electronic structure of discrete gold nanoclusters: Effects of composition, ligand, and solvent environment. A. Cirri, H. Morales, C. Kmiotek, C.J. Johnson

4:15 Intermission.

4:25 332. Coherent electronic dynamics in atomically precise nanoclusters. K.L. Knappenberger

Section G

Marriott Marquis San Diego Marina
Point Loma

Charge & Substrate Transport in 3D Electrocatalytic Materials Cosponsored by CATL and ENFL A. Hall, C. C.

McCrory, Organizers
V. Thoi, Organizer, Presiding

1:30 Introductory Remarks.

1:35 333. Designing catalysts for water splitting based on electronic structure considerations. S. Banerjee

2:00 334. How do interactions between protic cations and polarized bismuth cathodes control the pathway of CO2 reduction?. J. Rosenthal

2:25 335. Accessing 3-D in transition-metal phosphide catalysts for water splitting: Challenges and opportunities. C. Acquah, S. Mutinda, R. Liyanage, D. Li, S.L. Brock

2:50 336. Modulating electrode- electrolyte interfaces for energy conversion reactions. V. Thoi

3:15 Intermission.

3:30 337. Water electrolysis on metal oxides for energy conversion: Materials and mechanisms. P. Strasser

3:55 338. Interfacing metals and compounds for enhancing hydrogen electrochemistry. Y. Sun 4:20 339. Tailoring the surface of metal nanoparticles for selective electrocatalysis. C.W. Li

Section H

Marriott Marquis San Diego Marina
Cardiff

Lanthanide & Actinide Chemistry

A. De Bettencourt Dias, Organizer K. Carter, D. Mills, Presiding

1:30 340. Electronic structures of bent, formally two-coordinate lanthanide(III) cations. H. Nicholas, M. Vonci, C. Goodwin, S. Loo, S. Murphy, D. Cassim, R.E. Winpenny, E. McInnes, N. Chilton, D. Mills

1:50 341. New insights into solid-phase transformations in the uranyl peroxide system. T.L. Spano, A. Miskowiec, J.L. Niedziela, M.W. Ambrogio, B.B. Anderson

2:10 342. Uncovering unprecedented uranium species: From water-stable uranyl(V) to U(IV) POM clusters. R. Faizova, L. Chatelain, R. Scopelliti, M. Mazzanti

2:30 343. Guest-dependent single- crystal-to-single-crystal phase transitions in a two-dimensional uranyl-based metal–organic framework. S. Hanna, X. Zhang, K. Otake, R.J. Drout, P. Li, T. Islamoglu, O.K. Farha

2:50 344. Synthesis of an unusual square planar Th(III) complex. D.N. Huh, J.W. Ziller, W.J. Evans 3:10 Intermission.

3:20 345. Interactions of unsaturated hydrocarbon ligands with low valent uranium centers. J.M. Boncella, A.M. Tondreau, B.S. Billow

3:40 346. Tuning reactivity of nitride bridged uranium complexes with amide and siloxide ligands. C.T. Palumbo, L. Barluzzi, R. Scopelliti, M. Mazzanti

4:00 347. Reactivity of uranyl triperoxide monomers. A. Arteaga, N. Martin, L.N. Zakharov, M.D. Nyman

4:20 348. Structural chemistry of uranium(IV)-furoate complexes. N.A. Vanagas, K.E. Knope

4:40 349. Organometallic chemistry of lanthanides: Oxidation states in trompe l’oeil and magnetic sandwiches. G. Nocton

5:00 350. Condensed and gas phase coordination chemistry of bioinspired chelators with early actinides. K. Carter, J. Jian, M. Pyrch, T. Forbes, W. Dejong, J.K. Gibson, R.J. Abergel

TUESDAY MORNING

Section A

Marriott Marquis San Diego Marina
Marina Ballroom Salon F

ACS Award in Pure Chemistry: Symposium in Honor of Danna Freedman
Cosponsored by PHYS

H. Karunadasa, J. Zadrozny, Organizers, Presiding

8:30 Introductory Remarks.

8:35 351. Applications of coordination chemistry principles to molecular magnetism. K.R. Dunbar

9:00 352. Giant spins as magnetic nodes and building blocks. T. Betley

9:25 353. Rationalizing the magnetism of multinuclear single- molecule magnets containing strong single-ion sources of anisotropy through the use of the anisotropic building unit [ErCOT]+(COT2– = 1,3,5,7- cyclooctatetraenide dianion). J.D. Rinehart, J. Hilgar, M.G. Bernbeck, A.K. Butts

9:50 354. Quantum magnetism enabled by chemistry: From quantum spin liquids to topological spin waves. Y. Lee

10:15 Intermission.

10:30 355. Let’s get together! Making bonds between small molecules at multimetallic centers. L.J. Murray

10:55 356. Quantum sensing using diamond color centers. H. Park

11:20 357. Award Address (ACS Award in Pure Chemistry sponsored by the Alpha Chi Sigma Fraternity and the Alpha Chi Sigma Educational Foundation): Approaching challenges in physics

MONDAY EVENING

Placeholder

Sci-Mix

S. A. Koch, N. S.

Section A

with inorganic chemistry. D.E. Freedman, M.J. Amdur, K. Collins, S. Coste, M. Fataftah, R.A. Klein, D. Laorenza, T. Pearson, S. Petry, A. Tamerius, C. Yu, A. Altman, L. Sun, J.P. Walsh, J. Zadrozny, M. Graham, S. Clarke

Section B

Marriott Marquis San Diego Marina
Solana

Chemistry of Materials: Nanomaterials
C. G. Lugmair, Organizer
E. A. Hernandez-Pagan, M. A. Mahmoud, Presiding

8:30 358. Single-component quasicrystalline nanocrystal superlattices by the flexible polygon tiling rule. Y. Nagaoka, O. Chen, H. Zhu

8:50 359. Synthesis of ZnS quantum dots: Towards shelling and heterostructures. E. Bennett, J.S. Owen

9:10 360. Correlated series of Au/Ag nanoclusters revealing the evolutionary patterns of asymmetric Ag doping. Y. Li

9:30 361. Size-controllable and uniform gold bumpy nanocubes for single-particle-level surface enhanced Raman scattering sensitivity. Y. Lee, K. Nam

9:50 362. Modulation of tungsten precursor reactivity for control over size and phase of WSe2 nanocrystals. J.Q. Geisenhoff, A.M. Schimpf

10:10 Intermission.

10:25 363. Expanding colloidal hybrid nanoparticles to metal phosphide systems. E.A. Hernandez-Pagan, R.E. Schaak

10:45 364. Photoreduction of iron oxide nanocrystals. H. Jung, B. Zhou, A.M. Schimpf

11:05 365. Asymmetric deposition of platinum atoms on gold nanorods induced by a substrate for synthesis of anisotropic bimetallic nanostructures. M.A. Mahmoud

11:25 366. Triplet exciton transfer in PbS/CdS core-shell quantum dots with surface-appended chromophores. C.M. Papa, S. Garakyaraghi, F.N. Castellano

Section C Marriott Marquis San Diego

Marina
Marina Ballroom Salon D

Chemistry of Material Lectureship & Best Paper Award

J. M. Buriak, A. De Bettencourt Dias, C. Toro, Organizers, Presiding

8:30 Introductory Remarks. 8:35 367. Functional properties from molecular dynamics in hybrid perovskite halides. E. Mozur, I.W. Oswald, A. Koegel, A. Maughan, J.R. Neilson

9:10 368. Competing interactions: Octahedral tilting, organic- inorganic coupling, and charge transport in vacancy-ordered double perovskites. A. Maughan, A. Ganose, A.M. Candia, J. Granger, D.O. Scanlon, J.R. Neilson

9:45 369. Atomic pair distribution function (PDF) analysis of nanostructured and disordered materials. S. Billinge

10:10 Intermission.

10:20 370. Tuning the bandgaps of halide double perovskites. A. Slavney, B. Connor, L. Leppert, J. Neaton, H. Karunadasa

10:45 371. Defect and carrier transport properties of emerging bismuth based photovoltaics. A. Ganose

11:10 372. Structural complexities in solids: Understanding functionality through local distortions in perovskite and pyrochlore materials. G. Laurita

11:35 373. Key structural and chemical features of defect-tolerant semiconductors. P. Gorai

Section D

Marriott Marquis San Diego Marina
Marriott Grand Ballroom Section 9

Inorganic Chemistry for Sustainable Energy & Environment

L. A. Berben, Organizer S. C. Marinescu, Presiding

8:30 374. Strategies to enhance electrochemical ammonia production on the surfaces of non- noble metal electrocatalysts. Y. Jang, K. Choi

9:00 375. CO2 as a trigger for controlling the properties of surfaces and coatings. P.G. Jessop, M.F. Cunningham

9:30 376. Developing alternatives to oil as feedstocks for our chemicals and liquid fuels. K.I. Goldberg

10:00 Intermission. 10:20 377. Metal-organic frameworks in light harvesting and energy transfer. A.J. Morris, P. Usov, S. Shaikh

10:50 378. Renewable methane from green energy and CO2: Commercial-scale solution to decarbonize our planet with biological methanation. M.B. Hein

Section E

Marriott Marquis San Diego Marina
Santa Rosa

Emerging Research in Molecular Synthesis

A. C. Brewer, J. M. Hoover, J. Y. Yang, Organizers
V. A. Schmidt, Organizer, Presiding
M. Emmert, Presiding

8:30 379. Beyond static DFT calculations for organometallic reactions in catalysis. D.H. Ess

9:00 380. Cu-catalyzed MLCT enabled photocycloadditions of non-conjugated pi-systems. V.A. Schmidt

9:30 381. Development of the copper-catalyzed carboamination reaction. K.L. Hull

10:00 Intermission.

10:15 382. Developing data-driven reaction analysis tools for reaction optimization and interrogation. M.S. Sigman

10:45 383. Mechanistic insights into Fe catalyzed late-stage functionalization of amine C-H bonds. M. Emmert, C.J. Legacy, M. Frenette, F. Greenaway

11:15 384. Catalyst development for the decarboxylative functionalization of (hetero)arenes. J.J. Topczewski, R. Daley, E. Liu

Section F

Marriott Marquis San Diego Marina
Marriott Grand Ballroom Section 8 Surface Chemistry & Structure in Ligand Protected Nanoparticles

C. J. Johnson, B. Lear, Organizers A. Cirri, Presiding

8:30 385. How many organic molecules are there on gold nanocrystals? Results from both imaging and NMR. C.J. Murphy

9:15 386. Visualizing dynamic reorganization of surface-bound ligands on gold nanorods. K.A. Willets

10:00 Intermission.

10:10 387. Ligand control of the electronic structure near the Fermi energy in metallic nanoparticles. B.J. Lear

10:40 388. Elucidating the role of ligand functionality in phosphine- protected gold clusters using mass spectrometry. G.E. Johnson, J. Laskin, H. Hernandez

11:10 Intermission.

11:20 389. Dimensionality in surface functionalization. D.P. Goronzy, T. Base, K.N. Houk, P.S. Weiss

Section G

Marriott Marquis San Diego Marina
Marina Ballroom Salon G

Charge & Substrate Transport in 3D Electrocatalytic Materials
Cosponsored by CATL and ENFL A. Hall, V. Thoi, Organizers
C. C. McCrory, Organizer, Presiding

8:30 390. Using polymer encapsulation to influence the mechanism, activity, and selectivity of electrocatalytic CO2 reduction by molecular catalysts. C.C. McCrory

8:55 391. Developing materials to promote substrate channeling of intermediates in electrocatalytic cascades. S.D. Minteer

9:20 392. Ultrathin oxide overlayers for tunable electrocatalysis. D. Esposito

9:45 393. Exploiting transport limitations to enhance CO2-to-fuels selectivity. A. Wuttig, Y. Yoon, M. Schreier, S. Hall, Y. Surendranath 10:10 Intermission.

10:25 394. Making porous MOFs electrically conductive. J.T. Hupp, S. Goswami

10:50 395. Bridging homogeneous and heterogeneous catalysis with pincerMOFs. C.R. Wade, A. Kassie, B. Reiner

11:15 396. Redox hopping electron and ion transport in metal-organic framework materials. A.J. Morris, P. Celis Salazar, M. Cai

Section H Marriott Marquis San Diego
Marina Cardiff

Inorganic Catalysts

S. A. Koch, Organizer

8:30 397. Development of molecular electrocatalyst for CO2 reduction based on polypyridyl and nitrogen-based macrocyclic ligands. L. Lieske, A.L. Rheingold, C.W. Machan

8:50 398. Electrocatalytic reduction of dioxygen to hydrogen peroxide by a molecular manganese complex with a bipyridine-containing Schiff base ligand. S.L. Hooe, A.L. Rheingold, C.W. Machan, D. Dickie

9:10 399. Effect of s-block metal ion on redox properties of Mn(V) salen-crown ether complexes: Methane activation. A. Najafian, T. Cundari

9:30 400. Synthetic [2Fe2S] biomimietics in metallopolymers as hydrogen evolution electrocatalysts. K. Clary, M. Karayilan, R.S. Glass, J. Pyun, D.L. Lichtenberger

9:50 401. Systematic study of proton-coupled electron transfer in tris(triazolyl)borate mid-late 3d, 4d–transition metals complexes: Computational study. A. Nazemi, T.R. Cundari

10:10 402. Turning off hydrogen evolution: Effects of secondary sphere electrostatic interactions on catalyst product selectivity. J. Barlow, J.Y. Yang

10:30 Intermission.

10:40 403. Ionic strength of large polyions. D.L. Collins-Wildman, Y.V. Geletii, C.L. Hill

11:00 404. Pincer supported iron complexes for dinitrogen activation. A.M. Lugosan, D. Dickie, M. Zeller, W. Lee

11:20 405. Mechanism of photoreduction of CO2 to CH4 with iron-porphyrin catalyst. L. Dang, Z. Lu

11:40 406. Pd Single atom catalyst for small molecule transformations under practical conditions. G. Ding, Q. Zhang

12:00 407. Weaker interaction between second sphere and proton donor leads to increased selectivity and activity in Fe(III) Schiff base complexes for CO2 reduction to formate. A. Nichols, S. Hooe, C.W. Machan

12:20 408. Electrocatalysis with Ni(P2N2)2 complexes attached to the electrode through the phosphine moiety. F.M. Brunner, C.P. Kubiak

TUESDAY AFTERNOON

Section A

Marriott Marquis San Diego Marina
Marina Ballroom Salon F Chemistry of Materials: Synthesis & Properties

C. G. Lugmair, Organizer K. R. Kittilstved, C. E. Knapp, Presiding

1:30 409. Phenylalanine-based metallo-hydrogels with photo- switchable arylazopyrazole ligands. K.Y. Ghebreyessus, A. Sallee

1:50 410. Synthesis and optoelectronic properties of complex metal oxide A2M2O7 nanoparticles. Y. Mao

2:10 411. Trigonal bisdithiazolyl radicals as building blocks towards three-dimensional magnetic exchange networks. N.J. Yutronkie, D. Bates, P. Dube, S. Winter, C.M. Robertson, R.T. Oakley, J. Brusso

2:30 412. Revealing the speciation of dopant ions in metal thiophenolate clusters. F. Kato, K.R. Kittilstved

2:50 413. From molecules to materials: Effect of precursor design on functional device synthesis. C.E. Knapp, H.R. Tinker, Y. Zhou, M.A. Bhide, S.P. Douglas, K.L. Mears

3:10 Intermission.

3:25 414. Tunable cyclic Si-N hybrid materials. C.P. Folster, P.N. Nguyen, M.A. Siegler, R.S. Klausen

3:45 415. Tunable optical and magnetic properties in redox- switchable all-inorganic polyoxometalate frameworks. C. Lemmon, A.M. Schimpf

4:05 416. Tunable polyoxometalate-based frameworks: Synthesis, structural characterization, and modulation of optical and electronic properties. L. Chen, M. Turo, K. San, J. Wang, M. Gembicky, A.M. Schimpf

4:25 417. Synthesis of high-quality, single-crystalline polyoxovanadate- based frameworks. K.A. San, A.M. Schimpf

4:45 418. Sustainable synthesis of high purity silicon carbide with carbon fiber production residual and a sandstone. K. Sun, X. He, T. Wang, W. Lu, M. Fan

5:05 419. Electrochemically switchable zwitterionic metal- organic frameworks. J. Varghese, F. Dix, K. Duell, D. Aulakh, M. Ciobanu, M. Wriedt

Section B Marriott Marquis San Diego

Marina Solana

Learning from Nature: Earth- Abundant Metals for Oxidation Catalysis

T. A. Jackson, A.
Mukherjee, Organizers
S. S. David, Organizer, Presiding

1:30 420. Gas phase tackling of the oxo-wall. J. Roithova

2:00 421. Oxidation of hydrocarbons by high-valent metal- halide complexes. A.R. McDonald 2:25 422. Small molecule activation at transition metal centers: Structure-function correlations. K. Ray

2:50 Intermission.

3:00 423. Scope and mechanism of C-H bond activation by bio- inspired copper complexes and peroxides. A. Mukherjee, N. Singh, N. Botcha

3:25 424. Spectroscopic investigations of metal binding and oxygen activation in the heterobimetallic Mn/Fe R2lox proteins. H.S. Shafaat, E. Miller, C. Ghosh, J.M. Hazel, Z.R. Smith, N. Trivelas

3:50 425. Proton-coupled electron transfer mechanisms in copper- oxygen chemistry. W.B. Tolman 4:20 426. Adventures in exploring the high-valent nonheme iron-oxo landscape. L. Que

Section C

Marriott Marquis San Diego Marina
Marina Ballroom Salon D Chemistry of Materials: Metal Organic Frameworks

C. G. Lugmair, Organizer B. R. Barnett, D. C. Powers, Presiding

1:30 427. Influence of metal substitution on the pressure- induced phase change in flexible zeolitic imidazolate frameworks. C. McGuirk

1:50 428. Structural control of metal-organic framework bearing N-heterocyclic carbene precusor and immobilization of NHC-metal complexes. H. Kim, E. Lee

2:10 429. De novo synthesis of homo and heterometallic titanium organic frameworks with high- throughput methodologies. J. Castells-Gil, N. Padial, N. Almora- Barrios, C. Marti-Gastaldo

2:30 430. Particle size and defect control in nanoparticulate UiO-66 via modulator-free synthetic conditions. G.E. Decker, Z. Stillman, C.A. Fromen, E.D. Bloch

2:50 431. Responsive metal- organic frameworks incorporating redox-active Mo2(INA)4 molecular building units. F.J. Claire, M.A. Solomos, T. Kempa

3:10 Intermission.

3:25 432. Ultrathin films of layered coordination polymers: Charge transport and spin crossover at the nanoscale. V. Rubio-Giménez, G. Escorcia-Ariza, N. Almora-Barrios, M. Galbiati, C. Bartual-Murgui, S. Tatay, C. Marti-Gastaldo

3:45 433. Probing substrate diffusion in interstitial MOF chemistry with kinetic isotope effects. D.C. Powers

4:05 434. Leveraging π-basicity in metal–organic frameworks for ambient temperature hydrogen storage: Structural, thermodynamic and kinetic insights. B.R. Barnett, J.R. Long

4:25 435. Fabrication and characterization of a defect-free mixed matrix membrane by facile mixing PPSU with ZIF-8 core– shell microspheres for solvent- resistant nanofiltration. J. Dai, S. Li, L. Wang, J. Lei

4:45 436. Harnessing metal-metal interactions in metal organic framework based catalysts. S. Desai, J. Ye, T. Webber, T. Islamoglu, O.K. Farha, D.G. Truhlar, R. Penn, C.C. Lu

Section D

Marriott Marquis San Diego Marina
Marriott Grand Ballroom Section 9

Emerging Research in Molecular Synthesis

A. C. Brewer, J. M. Hoover, J. Y. Yang, Organizers
V. A. Schmidt, Organizer, Presiding

1:30 437. Carbenes as powerful transition metal surrogates. G. Bertrand

2:00 438. Accessing ambiphilic phosphine boronates by phosphine- directed C–H borylation. T.B. Clark, S.E. Wright, S. Richardson- Solorzano, K.C. Morris, W. Schumacher, T.N. Stewart

2:30 439. Manipulation of main group element fragments with transition metal isocyanides. J.S. Figueroa

3:00 Intermission.

3:15 440. Playing with charges: Electrostatically tethered reactive ion pairs. V. Lavallo

3:45 441. Main group-mediated olefin functionalization reactions. A.E. Wendlandt

Section E

Marriott Marquis San Diego Marina
Santa Rosa

Surface Chemistry & Structure in Ligand Protected Nanoparticles

B. Lear, Organizer
C. J. Johnson, Organizer, Presiding

1:30 442. Synthetic and postsynthetic chemistry of silver monolayer-protected clusters. T.P. Bigioni

2:00 443. Switchable surfactants for the preparation of monodisperse nanoparticles. S.R. Saunders, K. Bryant

2:30 444. Laser synthesis and spectroscopy of ligand-coated nanoclusters and nanomaterials. M.A. Duncan

3:00 Intermission.

3:10 445. Precise synthesis of platinum and alloy clusters and elucidation of their structures. Y. Negishi

3:55 446. Monitoring nanoparticle- driven chemistry with ultrafast surface-enhanced Raman spectroscopy. R.R. Frontiera

4:40 Intermission.

4:50 447. Surface chemistry and image dipoles in PbS quantum dots during resonant relaxation of excited intraband states. J.B. Asbury

5:20 Concluding Remarks.

Section F

Marriott Marquis San Diego Marina
Marriott Grand Ballroom Section 8

Charge & Substrate Transport in 3D Electrocatalytic Materials

Cosponsored by CATL and ENFL C. C. McCrory, V.
Thoi, Organizers
A. Hall, Organizer, Presiding

1:30 448. Enhancing the real-time detection of phase changes in lithium–graphite intercalated compounds through derivative operando (dOp) NMR cyclic voltammetry. A. Co, J. Lorie Lopez, P. Grandinetti

1:55 449. Accessing catalytically active ordered intermetallics electrochemically driven non- equilibrium phase transformations. A. Hall

2:20 450. Bicarbonate electroreduction in a flow cell. C.P. Berlinguette

2:45 451. Control over H+/OH– recombination in bipolar ion- exchange membranes enables extremely low overpotential reactivity for water dissociation or efficient light-driven ion pumping. W. White, R. Kautz, L. Schulte, S. Luo, R. Bhide, J. Glancy, L. Renna, S. Ardo

3:10 Intermission. 3:25 452. 3D design in electrocatalysis. N. Becknell, P. Papa Lopes, D. Jung, D. Strmcnik, N. Markovic, V. Stamenkovic

3:50 453. Understanding lithium- mediated ammonia synthesis. K. Manthiram, N. Lazouski, Z. Schiffer, K. Williams

4:15 454. Assembly of Au nanoparticles on Cu nanowires to tune CO2 reduction product from CO, C2H4 to CH3CHO. S. Sun

Section G

Marriott Marquis San Diego Marina
Marina Ballroom Salon G Coordination Chemistry: Characterization & Applications

A. Larsen, Organizer F. N. Castellano, C. J. Stein, Presiding

1:30 455. Photochemical upconversion with metal-to-ligand charge transfer sensitizers. F.N. Castellano

1:50 456. Water-soluble lanthanide (Eu, TB, Sm) bioprobes combining a pyclen or TACN framework and conjugated antennas for two- photon imaging. J. Shaya, N. Hamon, R. Tripier, O. Maury

2:10 457. Investigation of AlCl3- XCl (X = Cu, Ag) solutions in aromatics by 27Al NMR spectroscopy. W. Luo, Z. Liu, X. Meng, R. Zhang, H. Liu, C. Xu

2:30 458. Mimicking thiol gold nanoparticles with atomically- precise tunable organometallic equivalents. J. Stauber, E.A. Qian, J. Logan, D. Fujita, Y. Han, P. Kral, A.M. Spokoyny

2:50 459. Indium(III)complex of N, N’-bis(salicylidene) ethylenediamine as chemo-sensor for selective recognition of HSO4- and hemolytic toxicity (red blood cells) studies. T. Pandiyan, C.A. Huerta-Aguilar, S. Huerta-Jose

3:10 Intermission.

3:30 460. Copper-benzoquinoid coordination polymer as electrode material for lithium-ion batteries. C. Chang, T. Chen

3:50 461. Synthesis and reactivity of cobalt N-heterocyclic phosphenium/phosphido complexes. A. Poitras, C.M. Thomas

4:10 462. Orbital entanglement analysis of exchange-coupled transition-metal complexes. C.J. Stein, V. Krewald, D.A. Pantazis

Section H

Marriott Marquis San Diego Marina
Cardiff

Organometallic Chemistry: Synthesis & Characterization: Late Transition Metals

N. S. Radu, Organizer

1:30 463. Introducing the +1 oxidation state for derivatized 3d metallocene monoanions. C. Goodwin, M. Vonci, H. Nicholas, S. Greer, N. Chilton, D. Mills

1:50 464. Extrusion of dicobalt silicide cores via activation of all bonds at RSiH3 (R = H, Ph) by [(tris-Phosphinoborate)CoI]–. R.C. Handford, P. Smith, T. Tilley

2:10 465. Synthesis and reactivity of a rare Ni(I) methyl complex. R. Witzke, T. Tilley

2:30 466. Synthesis and characterization and reactivity of nickel(II)-calix[n]arene (n=4-6) complexes. J.A. Carter, B.A. Martinez Ortega

2:50 467. Formation of a Ni-C four-membered metallacycle and its reactivity toward X-Y bond activation. X. Xing, N.C. Tomson

3:10 468. Synthesis of cyclic (amino)(aryl)carbene copper(I) complexes. J. Lorkowski, U. Radius, C. Pietraszuk

3:30 469. Designing N-heterocycle functionalized phosphinoferrocene ligands. A. Sarbajna, B.E. Silva, A.L. Rheingold, D. Grotjahn

3:50 470. Coorindation of diatomic boron monofluoride to iron. M.J. Drance, J.S. Figueroa

4:10 471. Structure and Reactivity of Group IX Three-Coordinate Monoanions. M.L. Neville, C. Chan, J.S. Figueroa

4:30 472. Low valent cobalt isocyanides: Exploration of cobalt phosphide cluster building blocks. C. Chan, J.S. Figueroa

4:50 473. Readily accessible cyclic (alkyl)(amino)carbenes (CAACs). L.C. Oliveira, R. Jazzar, G. Bertrand

5:10 474. Synthesis and reactivity of a well-defined mixed-valent copper (0)/(I) nanocluster. J.L. Peltier, R.F. Jazzar, G. Bertrand

TUESDAY EVENING

Section A

Placeholder

Coordination Chemistry: Characterization & Applications

A. Larsen, Organizer

5:30 – 7:30

475. Synthesis, characterization, and antibacterial studies of Fe(III) complex of 3-nitro-N’-((3-hydroxy- 5-(hydroxymethyl)-2- methylpyridin-4-yl) methylene)benzohydrazide. V. Chittireddy

476. Rhenium(I) supramolecular rectangles for ion-sensing applications. S.A. Dhanpat, A. Kumar

477. Ligand-assisted dissolution of gold in organic solvents. E. Heliövaara, M. Räisänen, T. Repo 478. Polypyridine bridged ruthenium dimers as inner-sphere ketone transfer hydrogenation catalysts. C.H. Weeks, E.P. Kelson 479. Electrochemical and spectroelectrochemical studies of electrodes modified with ruthenium nitrosyl complexes. S.B. Ritter, M.J. Shaw

Section B

Placeholder

Coordination Chemistry: Synthesis & Characterization

A. Larsen, Organizer 5:30 – 7:30

480. Some MOFs with substituted biphenyldicarboxylic acid to show novel topologies. X. He, S. Zhang, D. Zhu

481. Preparation of mixed-metal thiocyanate of SnCu(SCN) for opto/electronic applications. C. Wechwithayakhlung, S. Horike, P. Pattanasattayavong

482. Synthesis and characterization of palladium mononuclear complexes with electron donor (N,O) species. C. Jimenez, J. Aviña, R. Guzmán-Mejía, R. Herrera, J. Gonzáles-campos

483. Perfect C3 symmetric sulfate complex with a urea-based hexafunctional synthetic receptor. A. Hossain, B. Portis, C.R. Johnson, M. Emami Khansari, A. Jahan, D.R. Powell

484. Effect of a coordinating pyridine moiety on the SAP and TSAP isomer proportions of bimodal Ln(III) complexes. M. Poveda, Z. Steinberg, O. Evbuomwan

485. Supramolecular architectures and coordination polymers based on metallacrown complexes: Magnetic and sorption properties. A.V. Pavlishchuk, M. Zeller, L. Carella, E. Rentschler, L.K. Thompson, A.W. Addison

486. Synthesis of fluorinated cobalt oxo cubanes: Catalysts for water oxidation. A. Rahman, T. Tilley

487. Synthesis of substituted bipyridylphosphine oxides via palladium(II) cross-coupling: Method development and application to coordination chemistry. T. Grutza, M. Bezpalko, W.S. Kassel

488. Synthesis of lanthanide molybdates via reaction of molybdenum(VI) oxide with aqueous acetate salts. K. Alrashidi 489. Synthesis, characterization, and electrochemistry of a ruthenium saloph nitrosyl complex. K. Shrestha, M.J. Shaw

490. Synthesis and characterization of a series of 5-methoxypyridyl- substituted phosphines and associated metal complexes. L. Warring, W.S. Kassel, M. Bezpalko

491. Synthesis and characterization of tris(2-pyridyl)phosphine oxide (OPPy3) complexes of select lanthanide(III) nitrates with potential application in molecular sensing. C. Cox, M. Bezpalko, W.S. Kassel

492. Anilino-pyridine ligand framework: Steric and electronic effects on the coordination chemistry to late transition metals. M. Bezpalko, W.S. Kassel

493. Systematic study of steric and electronic effects in substituted trispyridylphosphine ligands using molybdenum carbonyl complexes. J. Leonard, M. Bezpalko, W.S. Kassel

Section C

Placeholder

Environmental & Energy- Related Inorganic Chemistry

S. A. Koch, Organizer

5:30 – 7:30

494. Tetraphenylphosphonium metal halide perovskites synthesis and crystal structures. S.A. Althobaiti

495. Electrocatalytic reduction of carbon dioxide at a 2D rhenium covalent organic framework. M. Rahman

496. Electrocatalytic alcohol oxidation by Co(3-x)MxO4 catalysts. M. Riehs, S.E. Michaud, C.C. McCrory

497. Time dependence of iron- binding compound production in marine microorganisms under competitive growth conditions. J.D. Martin, S. Littlejohn, K. Brown

498. Tin polyesters: Polyimide blends as a dielectric material for energy storage application. A.A. Deshmukh, S. Nasreen, M. Baczkowski, G.M. Treich, M. Tefferi, C. Anastasia, Y. cao, G. Sotzing tunability europium(II)-containing visible-light photocatalysts. R. Barraza, M.J. Allen

506. Lanthanide extraction from fly ash using coordination chemistry. J. Hovey, M. Dardona, T.M. Dittrich, M.J. Allen

507. Slow magnetic relaxation in mono- and multinuclear uranium metallocene complexes. D. Lussier, M. Boreen, K. Chakarawet, J. Arnold, D.K. Shuh, J.R. Long

508. Lanthanide- and Ln doped bismuth- organic complexes: Structural motifs, visible excitation, and luminescence color tuning via dual emission pathways. R.L. Ayscue, C. Verwiel, K.E. Knope

509. F-element Fagan-Nugent coupling chemistry. J.K. Pagano, K.A. Erickson, J.L. Kiplinger

510. Organoactinide complexes of uranium and neptunium. A. Myers, J.R. Walensky

511. Comparative insertion reactivity of small molecules into thorium-nitrogen and thorium- phosphorus bonds. M. Tarlton, J.R. Walensky

512. Functionalization of cyclooctatetraene aimed to improve erbium single molecule magnet behavior. A. Butts

Section D

499. Synthesis and their characteristics of 1,1-disubstituted- 2,5-bis{(trimethylsilyl)ethynyl}- 3,4-diphenyl-siloles. J.W. Lim, Y.T. Park

500. Binary zinc borates and their industrial use. D.M. Schubert, M.B. Jacobs

501. Full-color luminescent dimethylamino-substituted difluoroboron β-diketonate complexes as environment- sensitive probes. F. Wang, S. Chung, C.A. DeRosa, D. Song, C.L. Fraser

502. Antibacterial performance and mechanism of inorganic salt cations. Z. Ding, X. Zhao, Y. Zhang

503. 1,8-Naphthalenediol derived boronic esters and inclusion properties of the 4,4′-bipyridine based Lewis acid–base complexes with different aromatic guest molecules. C. Manankandayalage, C. Krempner

Placeholder

Main Group Chemistry

T. Hudnall, Organizer 5:30 – 7:30

Placeholder

Lanthanide & Actinide Chemistry

A. De Bettencourt Dias, Organizer 5:30 – 7:30

504. Synchrotron and electron microscopy microstructural characterization of PuO2. M.A. DeVore, J.L. Venzie, B.A. Powell, L.C. Shuller-Nickles, J. Fortner, M. Newville

505. Understanding the effect of ligand environment on the

Section E

Section F

513. Garlic based two photon nanoprobes for targeted triple- negative breast cancer imaging. S. Begum, A. Pramanik, K. Gates, Y. Gao, P.C. Ray

514. Continuous growth of iron- oxo clusters to iron oxide nanoparticles: Insights on iron oxide nanoparticle formation at the early stage. H. Chang, T. Hyeon

515. Holey graphene noble metal nanoparticle composites via crystalline polymer templated etching. D. White, S. Burkert, S. Hwang, A. Star

516. Microwave-assisted synthesis of Mn-and rare earth ion-doped CsPbX3 (X = Br, Cl) perovskite nanocrystals. K.Y. Ghebreyessus, L. Flagg, U. Hommeric

517. Controlling nanocomposite magnetism through magnetic

Placeholder

Nanoscience

B. G. Trewyn, Organizer

5:30 – 7:30

orientation within a polymeric matrix. T. Zand

518. Magnetic characterization of iron-doped polydopamine nanoparticles. K.S. Cay, J.D. Rinehart, P.C. Bunting, Y. Xie

519. High-performance superparamagnetic Co-Mn-Zn ferrite nanoparticles for magnetic hyperthermia therapy of cancer. J. Pan, P. Hu, J. Shi, Q. Wu

520. Fe- and Sn-doped titania nanoparticles for metal-ion battery applications. B.D. Fahlman, M.K. Islam

521. Microwave-assisted flow synthesis of titania nanotubes. Y. Luo, M. Calzado Delgado, K. Yeung

522. Investigation of the influence of sonochemical parameters and initial temperature study on (ZnxAgyInz)S2 synthesis mechanism. H. Jung, S. Sul, J. Jung, J. Park

523. Engineering pseudo spin valve magnetoresistance in colloidally prepared nanoparticle films. B. Zhou, J.D. Rinehart

524. Synthesis of barium ferrite nanoparticles for new magnetic materials. K.M. Kirkpatrick, P.C. Bunting, J.D. Rinehart

Section G

Placeholder

Organometallic Chemistry: New Ligand Platforms

N. S. Radu, Organizer 5:30 – 7:30

525. Dipyridylmethane derivatives as ligands for highly efficient iridium catalyzed sp3 C–H borylation. M.R. Jones, N.D. Schley

526. Synthesis and characterization of terpyridine intermediate and derivatives for metal coordination. M. Moghadasnia

527. Strong magnetic exchange in dinuclear transition metal-Me6tren single-molecule magnets facilitated by a radical bridging ligand. K. Chakarawet, J.R. Long

Section H

Placeholder

Organometallic Chemistry: Synthesis & Characterization: Late Transition Metals

N. S. Radu, Organizer 5:30 – 7:30

528. Ferrocene-based heteroscorpionate nickel complexes for atom transfer radical polymerization. S. Li, P. Diaconescu

529. Evidence of carbon dioxide insertion into palladium-phenyl complex. K. Zhang, W. Williams, D. Dickie, D.H. Ess, T.B. Gunnoe

530. Use of silyl-calixarene derivative compound as precursor for the synthesis of transition metallo-calixarene complexes. B.M. Olivo, B.A. Martinez Ortega

531. Synthesis, reactivity, and magnetism of carbene-cobalt complexes. A. Mantanona, K.S. Cay, J.D. Rinehart

532. Synthesis, characterization, and photophysical properties of platinum(II) complexes with thiophene and halide ligands. C. Mastrocinque, M. Greenberg, C.M. Anderson, J. Tanski

Section I

Placeholder

Organometallic Chemistry: Synthesis & Characterization: Early Transition Metals

N. S. Radu, Organizer 5:30 – 7:30

533. Aromatic substituent effects modulate catalytic activity of synthetic [NiFe]-Hydrogenase mimics. C.R. Forbes, L. Gan, N.S. Herringer, T.L. Groy, P. Tarakeshwar, A.K. Jones

534. Tantallafuran supported by a linked cyclopentadienyl-carboranyl ligand: Synthesis and structure. J. Yang, Z. Xie

535. Synthesis and characterization of precursors for the electrochemical deposition of refractory metals out of ionic liquids. C. Egger, R. Reich, O. Schneider, F.E. Kuehn

536. Synthesis and structures of thermolabile organotitanium monoalkyl phosphates: Solvent effect on nuclearity, utility as epoxidation catalysts and single- source molecular precursors for TiP2O7. S. Verma, G. Bhat, R. Murugavel

537. Experimental and computational mechanistic and structural studies on substituted bis(cyclopentadienyl)tantalum(v) trihydrides for hydrocarbon activation. S. Rehbein

Section J

Placeholder

Solid-State Inorganic Chemistry

C. G. Lugmair, V. Poltavets, Organizers

5:30 – 7:30

538. Establishing the complex crystal chemistry of the coinage metals through synthesis, computation, and data-driven analysis. S. Lotfi, A. Mansouri Tehrani, J. Brgoch

539. Synthesis of ternary metal tetrel-pnictides using arc-melted precursors. G. Akopov, J. Mark, B. McBride, K. Kovnir

540. Tuning the thermoelectric properties of 2D layered GeAs. S. Lee, B. Owens-Baird, K. Kovnir 541. New ternary transition metal selenide Na2MoSe4: Computational and experimental study. E.I. Palos, R.I. Hernández Lima, J. Guerrero Sánchez, G. Alonso Nuñez, A. Reyes Serrato

542. Flexible and hierarchical structured MnO2@ZrO2 nanofibrous membranes with high catalytic performance. X. Zhang, X. Wang, J. Yu, B. Ding

WEDNESDAY MORNING

Section A

Marriott Marquis San Diego Marina
Marina Ballroom Salon F

Environmental & Energy- Related Inorganic Chemistry

S. A. Koch, Organizer A. J. Morris, Presiding

8:30 543. Electrocatalytic water oxidation by a trinuclear copper complex. A. Geer, X. Jia, B.A. McKeown, R.J. Nielsen, W.A. Goddard, T.B. Gunnoe

8:50 544. Electrocatalytic CO2 reduction by cobalt nis(pyridylmonoimine) complexes: Effects of ligand structure on catalytic activity. W. Nie, C.C. McCrory

9:10 545. Effects of surface modification of p-type silicon on the photoelectrochemical reduction of CO2 with group VII catalysts. C. Miller, S. Okuno, P. Cheung, C.P. Kubiak

9:30 546. Molecular control over excited-state supramolecular assembly. M. Turlington, L. Troian-Gautier, R. Sampaio, E.E. Beauvilliers, G.J. Meyer

9:50 547. Sustainable simplified process for production of vanadium oxides (V2O5, VO2, and V2O3). H.S. Devi, A. Mishra, M.S. Reza, M. Singh

10:10 Intermission.

10:15 548. Mixed-valency across supramolecular systems: Stabilizing soft interactions with electron delocalization. J.M. Palasz, F.M. Brunner, C.P. Kubiak 10:35 549. Enhancing Si(111) photocathode performance with surface dipoles and surface density of states. M.J. Rose, D. Boucher

10:55 550. Copper-dioxygen chemistry using novel tren-based, tris(phosphinimine) ligands. A. Weberg, N.C. Tomson, S. McCollom

11:15 551. Design and studies of novel iron-based complexes for hydrogen photo-evolution. A. Aydogan, O. Schott, G. Hanan, M. Singleton, B. Elias

11:35 552. Taming a high valent tetra-nickel cluster for PCET of small molecules. S. Jacob, G. Menard

11:55 553. High nuclearity Co/Mn oxo clusters: Potential water oxidation catalysts. P. Mahalay, G. Maayan, K.A. Abboud, G. Christou

Section B

Marriott Marquis San Diego Marina
Solana

Bioinorganic Chemistry: Proteins & Enzymes & Model Systems

S. A. Koch, Organizer T. Karabencheva- Christova, Presiding

8:30 554. Structural and spectroscopic insights into the reaction mechanism of carotenoid cleaving oxygenases. P. Kiser, E.R. Farquhar

8:50 555. Spectroscopic insights into the unusually high reactivity of the S = 1 [FeIV(O)(Me3NTB)]2+ complex that shed light on the oxidation mechanism of ferryl complexes. S. Banerjee, W. Rasheed, L. Que

9:10 556. Cu-dependent hydroxylation combined with 6- membered intramolecular cyclization under benign reaction conditions. R. Trammell, I. Garcia-Bosch, A. Cordova, P. Polunin, B. Blackmore

9:30 557. Genomic analysis of siderophore Fe(II)/α-ketoglutarate- dependent Aminoacyl β- Hydroxylases reveals functional subtypes. Z.L. Reitz, A. Butler 9:50 558. Mechanistic investigation of stereoselective olefin cyclopropanation catalyzed by an engineered carbene transferase. A. Tinoco, R. Fasan

10:10 Intermission.

10:30 559. Modeling copper active sites in biology: Synthesis and reactivity of bioinspired mononuclear copper(II) complexes. T. Jones, A. Mukherjee

10:50 560. Solvation dynamics at a surface loop of lipoxygenase and its relationship to catalytic proton- coupled electron transfer. J. Zaragoza, J. Klinman

11:10 561. Insights into the linkage between the catalytic reaction cycle and proton pumping in ba3 cytochrome c oxidase: combining DFT, electrostatics, molecular dynamics, and new X- ray structures. L. Noodleman, W. Han Du, Y. Chen, D. McRee, K. Hartfield, A.W. Goetz, T. Goh, T. Doukov, A. Cohen, V. Cherezov, M. Soltis, P. Padayatti

11:30 562. Selective removal of endogenous CO in vitro and in vivo by aqueous hemoprotein model complexes. H. Kitagishi 11:50 563. Synthesis and characterization of heterobimetallic Fe–O–Mn complexes: Modeling RNR 1c and R2lox. P. Crossland, A. Zhou, L. Que

12:10 564. Insights into non-heme iron and 2-oxglutarate demethylases by QM/MM and MD methods. T. Karabencheva- Christova, S.O. Waheed, R. Rajeev, C. Christov

Section C

Marriott Marquis San Diego Marina
Marina Ballroom Salon D

Organometallic Chemistry: Synthesis & Characterization: Early Transition Metals

N. S. Radu, Organizer

8:30 565. Stable ethylene-carbon dioxide group 6 metal complexes. P.J. Perez, M. Alvarez

8:50 566. Tungsten-ligand bond strengths for 2p elements, a DFT and ab initio study. C. Moulder, K. Kafle, T. Cundari

9:10 567. Organomanganese phosphine-phenol(ate) complexes: Coordination chemistry, and catalysis. K. Kadassery, S.N. MacMillan, D.C. Lacy

9:30 568. Synthesis and characterization of mono(oxazoline)-substituted cyclopentadienyl zirconium complexes. Y. Chu, N. Eedugurala, A.D. Sadow

9:50 569. Organometallic complexes of early transition metals supported by bulky acetylacetonate ligands. S.M. Krajewski, M.P. Marshak

Section D

Marriott Marquis San Diego Marina
San Diego Ballroom Salon C

Chemistry of Materials: Metal Organic Frameworks

C. G. Lugmair, Organizer
E. D. Bloch, J. Rimsza, Presiding

8:30 570. Theoretical study of porphyrin-based MOF structure for storage, separation, and drug delivery applications. R. Belosludov

9:10 571. Gold nanoparticles in the NU-1000 metal organic framework: Structures and O2 activation. R.D. Senanayake, R. Snurr, C.J. Cramer

9:30 572. Hierarchical self- assembly of supramolecular coordination polymers using giant metal-organic nanocapsules as building blocks. C. Zhang, F. Wang, R. Patil, C.L. Barnes, T. Li, J.L. Atwood

9:50 573. Liquid-phase separations of fluoroarenes in metal-organic frameworks. P.J. Milner, M. Gonzalez, J.R. Long

10:10 Intermission.

10:25 574. Gas storage in porous coordination cages. E.D. Bloch

10:45 575. Low-valent coordination networks with m- terphenyl isocyanides based linkers. A. Arroyave

11:05 576. Probing metal–organic framework growth process with competitive nucleation. M.C. Wasson, J. Lyu, T. Islamoglu, O.K. Farha

11:25 577. Acid gas adsorption and structural characterization of RE- DOBDC MOFs via density functional theory. D.J. Vogel, T.M. Nenoff, J. Rimsza

Section E

Marriott Marquis San Diego Marina
Santa Rosa

Chemistry of Materials: Nanomaterials

C. G. Lugmair, Organizer S. Chen, Y. Mao, Presiding

8:30 578. Kinetically controlled sequential seeded growth as a route toward metal dendrimers. J.D. Smith, M.M. Scanlan, S.E. Skrabalak

8:50 579. Tunable library of aminophosphines provides mechanistic insights on InP nanocrystal nucleation and growth. B. McMurtry, J. De Roo, J.K. Teglasi, K. Qian, A. Swarnakar, J.S. Owen

9:10 580. Scalable solid-state synthesis of SnS2/graphene nanostructured hybrids for high performance supercapacitor applications. S. Al Hassan, S. Lonkar, V. Pillai

9:30 581. Synthesis and characterization of nanoscale europium barium titanate (Eu0.5Ba0.5TiO3). N. Farahmand, S. O’Brien, J. Lombardi, F.A. Pearsall, L. Yang, S.J. Billinge, Z. Gai

9:50 582. Crystallinity and size control of colloidal germanium nanoparticles from organogermanium halide reagents. B. Pescara, K. Mazzio, K. Lips, S. Raoux

10:10 583. Transformation of cuprous oxide microcrystals into hollow copper nanoshells by facet- selective extraction of photoexcited charges. C. Qin, B. Campbell, M. Shen, T. Zhao, B. Sadtler

10:30 Intermission.

10:35 584. Mesoporous silica coated CuFe2O4 nanoparticles: Synthesis, characterization and application in gas phase H2S removal. G. BASINA, D. Abdullah Ali Gaber, S. Abdullah Ali Gaber, V. Tzitzios, C. Gioti, A. Mourkas, I. Ismail, I. Panagiotopoulos, M.A. Karakassides, Y. Fowad AlWahedi

10:55 585. Enzyme immobilization with reduced confinement in metal- organic frameworks. S. Chen, W. Lo, L. Chou, F. Shieh, C. Tsung 11:15 586. Molten-salt synthesis of pyrochlore RE2Hf2O7 nanoparticles. Y. Mao, M. Pokhrel, K. Wahid, S. Gupta

Section F

Marriott Marquis San Diego
Marina
Marina Ballroom Salon E

Coordination Chemistry: Synthesis & Characterization
A. Larsen, Organizer
T. Betley, M. Stollenz, Presiding

8:30 587. Correlation of formal oxidation state with the N-N bond distance of chromium dinitrogen complexes. F. Ahmadi Darani, K.H. Theopold

8:50 588. Aromaticity in bis(imino)pyridine complexes. T. Bass, T.J. Sherbow, C.R. Carr, L.A. Berben

9:10 589. Interaction between bimetallic sites in bimetallic composite ionic liquids. Y. Zhang, X. Meng, R. Zhang, H. Liu, C. Xu, Z. Liu

9:30 590. Heteroleptic calladium(II) complexes of the redox-active propentdyopent scaffold supported by intramolecular hydrogen bonding. C. Curtis, E. Tomat

10:10 Intermission.

10:15 591. To multiply bond or not. T. Betley

10:35 592. Investigation on the stability of a series of BODIPYs in acidic conditions: Experimental and computational study into the role of the substituents at boron. M. Wang, D.R. Mason, P.N. Bobadova-Parvanova, M. Vicente 10:55 593. Synthetic investigation of competing magnetic interactions in 2D metal-organic frameworks. K. Collins, M. Fataftah, D.E. Freedman

11:15 594. Lewis-acid-catalyzed BODIPY boron functionalization utilizing trimethylsilyl nucleophiles. G. Zhang, M. Wang, F.R. Fronczek, K.M. Smith, M. Vicente

Section G

Marriott Marquis San Diego
Marina
Marina Ballroom Salon G

Inorganic Catalysts

S. A. Koch, Organizer

8:30 595. New classes of homo- and heteroleptic Cu(I) metal-to- ligand charge transfer photosensitizers. F.N. Castellano

8:50 596. Real-time detection of large Abeta oligomers using photoluminescence anisotropy. B. Jiang, A. Aliyan, A. Smith, A. Marti, I. Gonzalez-Moreno

9:10 597. Delayed photoluminescence in metal- conjugated fluorophores. M. Yang, M. Zamkov, H.M. Mattoussi

9:30 598. Methane C–H activation via cyclic (alkyl)(amino)carbenes (CAACs) and CAAC- supported transition metal complexes: Computational study. Z. Sun, T.R. Cundari

9:50 599. Photoinitiated oxidation of halides to halogen using ruthenium trisbipyridyl complexes as catalysts. C. Chen, I. Chang 10:10 600. New approaches to hydrocarbon feedstock conversion: Bifunctional Pd complexes for tunable heterolytic C-H activation. R. Tenney, W. Christman, N. Arulsamy, E.B. Hulley

10:30 601. High-throughput screening of MOF catalysts. J. Palomba, S. Cohen, M. Kalaj 10:50 Intermission.

11:00 602. Molecular cobalt complexes with pentadentate ligands for electro- and photocatalytic hydrogen generation in aqueous solution. P. Wang, G. Liang, E. Towles, D. Li, C. Boyd, K. Hill, B. Shaver, W. Grubbs, C.E. Webster, X. Zhao

11:20 603. Electrochemical and computational investigation of aromatically bridged [2Fe-2S] clusters for electrocatalytic hydrogen production. M.O. Hamilton, J.M. Kiselka, M. Karayilan, R.S. Glass, J. Pyun, D.L. Lichtenberger

11:40 604. Effect of hydrogen bonds on photocatalysis of CO2 reduction. P. Cheung, T. Zeng, C.P. Kubiak

12:00 605. Chemically driven water oxidation by mononuclear Ru(II) complexes and deactivation pathway. A. Kundu, S. Mandal 12:20 606. Synthesis and reactivity studies of molybdenum(VI) and rhenium(V) oxo complexes as bioinspired oxo transfer catalysts. M. Hossain, J. Schachner, M.O. Haukka, A. Lehtonen, N. Mösch- Zanetti, E. Nordlander

Section H

Marriott Marquis San Diego
Marina Cardiff

Nanoscience

B. G. Trewyn, Organizer

8:30 607. Revealing the peculiar solubility of some atomically- precise gold nanoclusters. M.J. Cowan, T. Higaki, R. Jin, G. Mpourmpakis

8:50 608. Nonthermal plasma- synthesized PB co-doped Si NCs: New approach to non-toxic NIR- emitters. G. Pach, R. Limpens, N.R. Neale

9:10 609. Structural identification and quality assessment of graphene derivatives by X-Ray diffraction. I. Sengupta, S. S S Sharat Kumar, S. Pal, S. Chakraborty

9:30 610. Capitalization on self- assembly for the preparation of rhenium carbonyl-based nanoparticles for theranostic applications. K. Chan

9:50 611. Probing the interior nanoscale heating mechanism of a magnetic core in mesoporous silica drug-delivery nanoparticles using fluorescence depolarization. F. Lin, J.I. Zink

10:10 612. Mosquito bite prevention through graphene barrier layers. C. Castilho, D. Li, M. Liu, Y. Liu, H. Gao, R. Hurt

WEDNESDAY AFTERNOON

Section A

Marriott Marquis San Diego Marina
Marina Ballroom Salon F

Bioinorganic Chemistry: Proteins & Enzymes & Model Systems

S. A. Koch, Organizer
M. J. Rose, Presiding

1:30 613. Acid pKa-dependence O– O bond lysis of a nonheme FeIII– OOH species: Analogy to the formation of heme compound I. S. Xu, A. Darksharapu, W. Rasheed, L. Que

1:50 614. Investigating the mechanism of formation of a rare thiolate-ligated Fe(III)-sulfenate. A. Downing, M.N. Blakely, J. Kovacs

2:10 615. Functional hydride transfer in anthracene scaffold- based synthetic models of [Fe]- hydrogenase. M.J. Rose, S. Kerns, J. Seo

2:30 616. Investigation of the binding of nitrogen-based exogenous ligands in iron complexes within a C3-symmetrical phosphinic amide tripodal ligand. C. Sun, A. Borovik

2:50 617. From organometallic carbides to nitrogenase-inspired clusters: Sulfurization of Fe6 and Fe5Mo carbides. M.J. Rose, C. Joseph

3:10 Intermission.

3:30 618. Artificial iron proteins using biotin–streptavidin technology. K. Miller, A. Borovik

3:50 619. Tetranuclear Mn4O4 complexes as models of the oxygen evolving complex of photosystem II. A. Shiau, H. Lee, P. Oyala, T. Agapie

4:10 620. Spectroscopic characterization of thiolate ligated iron-dioxygen and oxo-atom donor intermediates. M. Dedushko

4:30 621. Fluorescent probes for New Delhi metallo-β-lactamases to explore bacterial zinc homeostasis. R. Mehta, P. Thomas, W. Fast, E.L. Que

4:50 622. High valent non-heme iron-oxido and -hydroxido complexes. J. Lee, V. Oswald, S. Biswas, M.P. Hendrich, A. Borovik 5:10 623. Principles of metal selectivity bias and cluster assembly in metallothionein metal thiolate clusters. J.S. Calvo, N. York, B.S. Pierce, G. Meloni

Section B

Marriott Marquis San Diego Marina
Solana

Chemistry of Materials: Materials for Energy & Catalytic Applications

C. G. Lugmair, Organizer A. J. Karkamkar, R. M. Kennedy, Presiding

1:30 624. Facile solvent free synthesis of iron porphyrin COFs for CO2 reduction. P. Cheung, S. Lee, C.P. Kubiak

1:50 625. Covalent organic frameworks composed of rhenium bipyridine and metal porphyrins: Designing heterobimetallic frameworks with two distinct metal sites. E. Johnson, R.M. Haiges, S.C. Marinescu

2:10 626. Surface-immobilized conjugated polymers incorporating rhenium bipyridine motifs for electrocatalytic and photocatalytic CO2 reduction. N.M. Orchanian, L.E. Hong, J. Skrainka, J. Esterhuizen, D. Popov, S.C. Marinescu

2:30 627. Electrocatalytic CO2 reduction in water using Re complex catalyst with polymer ion gels electrode. S. Sato, B.J. Mcnicholas, R.H. Grubbs

2:50 Intermission.

3:05 628. Catalytic hydrogenation of CO2 to methanol using tandem catalysis involving encapsulated ruthenium complexes in the metal- organic framework UiO-66. T. Rayder, E.H. Adillon, C. Tsung, J.A. Byers

3:25 629. Catalytic upcycling of waste polymers by supported metal catalysts. R.M. Kennedy, G. Celik, R. Hackler, S.C. Ammal, M. Ferrandon, A.M. LaPointe, A.D. Sadow, A. Heyden, K.R. Poeppelmeier, M. Delferro

3:45 630. CO2 reduction to CO by rhenium catalyst and various attachment strategies to carbon electrode surfaces. A. Zhanaidarova, C.P. Kubiak

4:05 631. Alternative ammonia storage materials for SCR of NOx. A.J. Karkamkar

4:25 632. Exploration of p-type delafossite CuMO2 oxides as photocatalysts. Y. Mao

4:45 633. Electron localization and transport through ruthenium polypyridyl dye-sensitized core/shell SnO2/TiO2 mesoporous thin films. E. James, M. Bennett, G.J. Meyer

Section C

Marriott Marquis San Diego Marina
Marina Ballroom Salon D Chemistry of Materials: Metal Organic Frameworks

C. G. Lugmair, Organizer M. I. Gonzalez, M. Wriedt, Presiding

1:30 634. Metal-organic frameworks as templates for the controlled growth of catalytically active copper nanoparticles. L. Redfern, O.K. Farha

1:50 635. Controlled encapsulation of biomolecules into nanoporous materials. C. Tsung

2:10 636. Confinement of atomically-defined metal halide sheets in a metal–organic framework. M.I. Gonzalez, A. Turkiewicz, L.E. Darago, J. Oktawiec, K. Bustillo, F. Grandjean, G.J. Long, J.R. Long 2:30 637. Framework structure defines the excitonic properties of mo fs. P. Deria, J. Yu

2:50 638. Synthesis and enhanced performance of metal–organic framework hybrid materials. Y. Liu, S. Klein, K. Nelms, J. Sosa 3:10 Intermission.

3:25 639. Old linkers new tricks: Evolution of 14-Connect Zr6 secondary building units. M.J. Hurlock, Q. Zhang

3:45 640. Photodoping as a route to storing electrons in metal–organic frameworks. C.H. Hendon

4:05 641. Energy and charge transfer dynamics in porphyrin: MOF composite. X. Li, J. Yu, P. Deria

Section D

Marriott Marquis San Diego
Marina
San Diego Ballroom Salon C

Organometallic Chemistry: Catalysis – Late Transition Metals

N. S. Radu, Organizer

1:30 642. Rhenium bipyridine catalysts with hydrogen bonding pendant amines for CO2 reduction. A. Hellman, S.C. Marinescu, R.M. Haiges

1:50 643. Generation of active palladium(0) catalyst species from air-stable palladium(II) precatalysts and their application in cross- coupling reactions. K.H. Shaughnessy

2:10 644. Novel metal-catalyzed nitrene transfer reactions: Increasing molecular complexity. P.J. Perez, M. Diaz-Requejo, M.R. Rodríguez, A. Moreno

2:30 645. Optimizing ene-yne metathesis reactions: Understanding how optimal conditions shift with substrate. K. Basemann, B. Schmidt, T.L. Windus, A.D. Sadow

2:50 646. Chasing copper hydrides. J.L. Peltier, E.A. Romero, d. munz, R.F. Jazzar, G. Bertrand

3:10 647. Co-catalytic effects in iron-mediated hydrogenation of electron-rich carbonyl compounds. U. Jayarathne, N. Hazari, W.H. Bernskoetter

3:30 648. Development of molecular electrocatalysts for energy-related transformations. K.M. Waldie, S. Katipamula, M. Zou, S. Warrier

3:50 649. Comparison of reactivity of iron alkoxide complexes towards azoarene synthesis. D. Wannipurage, S. Kurup, M. Yousif, S. Groysman, R.L. Lord

4:10 650. Development of group 9 transition metal based catalysts for the oxidative alkenylation of arenes. W. Zhu, J. Chen, X. Jia, D. Dickie, T.B. Gunnoe

Section E

Marriott Marquis San Diego Marina
Santa Rosa

Chemistry of Materials: Nanomaterials

C. G. Lugmair, Organizer M. Friedfeld, Presiding

1:30 651. Systematic tailoring of CdSe quantum dot-molecule composites for triplet energy transfer reactions. D.T. Yonemoto, F.N. Castellano

1:50 652. Conversion of InP clusters to nanomaterials and its role in the design of alloyed III-V nanomaterials for emissive applications. M. Friedfeld, J. Stein, D. Johnson, B. Cossairt

2:10 653. Nucleation kinetics and molecular mechanism in transition- metal nanoparticle formation: Intriguing, informative case of a bimetalic precursor, {[(1,5- COD)IrI(HPO4)]2}2-. C. Whitehead, R.G. Finke

2:30 654. Attaining tunability of colloidal copper phosphide nanocrystals through synthetic design and post-synthetic redox modulation. A. Rachkov, A.M. Schimpf

2:50 655. Functionalization of boron-nitride nanomaterials using reductive conditions. C.A. de los Reyes, K. Hernandez, C. Martinez, A. Smith McWilliams, M. Pasquali, A.A. Marti

3:10 Intermission.

3:25 656. Stitching quantum dots in formamide as an alternative route to make heterostructures. P. Moroz, M. Zamkov, J. Cassidy, D. Porotnikov

3:45 657. Synthesis and properties of ferroic and multiferroic transition/rare-earth metal oxide nanomaterials. J. Lombardi, F. Pearsall, N. Farahmand, L. Yang, J. Li, Z. Gai, S. Billinge, S. O’Brien

4:05 658. Applications of the nanoconfinement effect in explosive stabilization, chemical dosimeters, and water treatment. A.W. Apblett, N.F. Materer, E. Kadossov, R. Butt

4:25 659. Colloidal CuFeS2 nanocrystals: Synthesis and insights into the intermediate Fe d- band that influences its optical properties. S. Ghosh, D.J. Milliron

Section F

Marriott Marquis San Diego Marina
Marina Ballroom Salon E

Coordination Chemistry: Synthesis & Characterization

A. Larsen, Organizer
R. Hernandez Sanchez, Presiding

1:30 660. Some novel bioactive carboxylate metal complexes: Synthesis, structural elucidation and antimicrobial properties. J.A. Obaleye

1:50 661. Ruthenium–cobalt oxo cubane bearing a terminal RuV– oxo. J. Amtawong, D. Balcells, J. Wilcoxen, N. Biggins, R. Britt, T. Tilley

2:10 662. Thermochromic properties of mixed anion crystals of bis(cyclohexyl isocyanide) gold(I) complexes. P.M. Luong, V. Moshayedi, M.M. Olmstead, A.L. Balch

2:30 663. Reaction of iron ions with 2-oximinocarboxylates: Kinetics of complex formation and the thermal conversion of the products to metal oxides. W. Alamier, A.W. Apblett

2:50 664. Atomically-defined nanoscale materials. R. Hernandez Sanchez

3:10 Intermission.

3:30 665. Questions of noninnocence and ease of azo reduction in diruthenium frameworks. F.F. Fatima Khan, G.K. Lahiri

3:50 666. Accessing a new molecular scaffold for Fe(II) spin- state switching through post- synthetic modification. B. Livesay, M.P. Shores

4:10 667. FeII spin-crossover complexes as temperature- and pH- responsive 19F chemical shift magnetic resonance probes. A.E. Thorarinsdottir, A.I. Gaudette, D. Harris

4:30 668. NHC–, CAAC–, and CDC–alkaline earth metal complexes as reagents for bond activation. L.A. Freeman, J. Walley, G. Wang, G. Breiner, D. Dickie, R.J. Gilliard

Section G

Marriott Marquis San Diego Marina
Marina Ballroom Salon G

Lanthanide & Actinide Chemistry

A. De Bettencourt Dias, Organizer D. A. Penchoff, D.
Stamberga, Presiding

1:30 669. Predicting stability constants for terbium(III) complexes with 4-substituted dipicolinic acid analogues using density functional theory. H. Chen, R. Shi, H. Ow

1:50 670. High-throughput screening to achieve benchtop separations for selected rare earth elements. J. Nelson, T. Cheisson, H. Rugh, M. Gau, P. Carroll, E.J. Schelter

2:10 671. Ion coupled plasma mass spectrometry detection of the isotachophoretic separation of nonradioactive lanthanides in a capillary and a microfluidic device. H.E. Lackey, D. Bottenus, S.D. Branch, M. Liezers, S.D. Shen, A. Lines

2:30 672. Complexation of lanthanides and actinides: Theoretical perspective on predicting binding selectivity. D.A. Penchoff, C. Peterson, G.K. Schweitzer, D.M. Jenkins, R. Harrison, H.L. Hall

2:50 673. Tetravalent cerium complexes and clusters. J.N. Wacker, A.S. Ditter, S.A. Kozimor, K.E. Knope

3:10 674. Crucial impact of cerium reduction on photoluminescence properties. R. Génois, R. Gautier, F. Massuyeau, S. Jobic

3:30 675. Isolation and assessment of the cytotoxicity of oligothienyl- based luminescent lanthanide complexes. K. Johnson, C.V. Rodrigues, M.O. Rodrigues, V.C. Lombardi, A. De Bettencourt Dias

3:50 676. Separation of rare earth elements using novel diglycolamide ligands. D. Stamberga, C. Albisser, M.R. Healy, K.L. Lyon, I. Popovs, S. Jansone-Popova

4:10 677. Highly functional rare Earth starting materials. R. Beattie, J.K. Pagano, K.A. Erickson, S.K. Cope, B. Scott, D.E. Morris, J.L. Kiplinger

4:30 678. Peroxide-selective O2 reduction via metal-coupled electron transfer with rare earth triflates. M.J. Lueckheide, M.Z. Ertem, J.R. Robinson

4:50 679. ErCOT: An anisotropic metal-ligand pair for targeted molecular magnet design. M.G. Bernbeck, J. Hilgar, J.D. Rinehart

Section H

Marriott Marquis San Diego Marina
Cardiff

Main Group Chemistry

T. Hudnall, Organizer R. J. Gilliard, C. E. Knapp, Presiding

1:30 680. Eclipsed digermylenes as building blocks to construct catenated multinuclear germanium chains and rings. Y. Wey, G. Huang, J. Yu, Y. Tsai

1:50 681. Cyclodiphosphazanes in metal–organic frameworks. M.S. Balakrishna

2:10 682. Inorganic rings of group 13 and 14 elements as a platform for molecular hybrid materials. W. Yang, K.E. Krantz, D. Dickie, R.J. Gilliard

2:30 683. Iron, cobalt, and nickel complexes with silylene ligands. C. Cui, Y. Bai

2:50 Intermission.

3:00 684. Investigations into the synthesis, reactivity, and thermolysis of heterobimetallic precursors. K.L. Mears, C.E. Knapp, C.J. Carmalt

3:20 685. Designer aluminium compounds for use as precursors in low temperature metal coatings. S.P. Douglas, C.E. Knapp

3:40 686. Synthesis and characterization of selenium and tellurium containing organic materials toward sensors and emitters. G. Hoover, B. Drummond, S. Jones, D. Credgington, D.S. Seferos

4:00 687. Precursor design, synthesis, and reactivity: Tuning molecules for low temperature conversion to functional materials. C.E. Knapp, H.R. Tinker, Y. ZHOU, M.A. Bhide, S.P. Douglas, K.L. Mears

THURSDAY MORNING

Section A

Marriott Marquis San Diego
Marina
Marina Ballroom Salon F

Chemistry of Materials: Synthesis & Properties

C. G. Lugmair, Organizer A. Hendrickson, Presiding

8:30 688. Fabrication and thermal behavior of metal matrix composites containing NTE ZrW2O8. Q. Zhang

8:50 689. Lead-free all-inorganic Ag doped cesium bismuth iodide perovskite for resistive switching with ultra-low operating voltage and high on/off ratio by preconditioned metal conducting filament. J. Han

9:30 690. Designer gallium precursors towards functional materials. K.L. Mears, C.E. Knapp, C.J. Carmalt

9:50 691. Synthesis and structural characterization of nano coordinated Cd(II) complexes. M. Raja

10:10 Intermission.

10:25 692. Ultrathin PdAg single- crystalline nanowires enhance ethanol oxidation electrocatalysis. H. Lv, Y. Wang, D. Xu, B. Liu 10:45 693. Accelerating the discovery of type II porous liquids using high-throughput automation. R. Kearsey, B.M. Alston, M.E. Briggs, R.L. Greenaway, A.I. Cooper

11:05 694. Synthesis and design of semiconductor-core crystalline Bragg fibers. A. Hendrickson, M. Coco, J. Krug, C. Mathewson, S.C. Aro, S. McDaniel, J. Mauro, P. Sazio, G. Cook, V. Gopalan, J.V. Badding

11:25 695. In silico design of new functional materials. V. Korolev, A. Mitrofanov, A. Eliseev, B. Sattarov, V. Tkachenko 11:45 696. Experimental screening for discovery of low dimensional metal halides with intense white- light emission. R. Gautier

Section B

Marriott Marquis San Diego
Marina Solana

Organometallic Chemistry: Applications to Materials & Polymer Science

N. S. Radu, Organizer

8:30 697. ‘Super-bulky’ ligands: Coordination chemistry and application in ring-opening polymerization reactions. C. Bakewell

8:50 698. Mechanistic and kinetic studies of ring-opening metathesis polymerization with third- generation Grubbs catalysts. D. Walsh, M. Hyatt, D. Guironnet

9:10 699. Chemical mapping and optimization of redox switchable metal complexes for ring-opening polymerization. A. Lai, N. Fey, P. Diaconescu

9:30 700. Electrochemically controlled redox-switchable ring- opening polymerization. Z. Hern, C. Liu, P. Diaconescu

9:50 701. Increasing stereocontrol in lactide polymerization with flexible catalysts. P. Daneshmand, F. Schaper

10:10 702. Redox switchable (co)polymerization reactions with a zirconium compound. R. Dai, P. Diaconescu

10:30 703. CVD functionalization of graphene using transition metal carbonyls: Facile route to generate bandgaps. K. Vinodgopal, K. Robinson, X. You, J. Atkin, M. Terrones, D. Grasseschi, S.C. Sendlinger

10:50 704. Nickel-based bimetallic catalysts for Olefin polymerization. S. Xiong, T. Agapie

11:10 705. Introducing complexity to polysilanes using fused ring building blocks: Poly(siladecalin). E. Marro, R.S. Klausen

Section C

Marriott Marquis San Diego Marina
Marina Ballroom Salon D

Chemistry of Materials: Materials for Energy & Catalytic Applications

C. G. Lugmair, Organizer V. Doan-Nguyen, R. Mishra, Presiding

8:30 706. Oxide ion conductors in the hexagonal perovskite family. A. Mclaughlin, E. Wildman, S. Fop

8:50 707. MOF crystal branching: Novel solution to counteracting plasticization in MOF-polymer mixed-matrix membranes. K. Zhang, B.J. Sundell, D. Harrigan, S.C. Hayden, W. Chi, Z. Smith 9:10 708. Dual functions of water in stabilizing the metal-pentazolate hydrates [M(N5)2(H2O)4]4H2O (M = Mn, Fe, Co, and Zn) high-energy density materials. M. Cheng

9:30 709. Quinone-based metal−organic materials for energy storage and gas separation. T. Chen

9:50 710. Nanoporous ceramic membranes for redox flow batteries. S. Candelaria, K.L. Corp, A. Salunkhe, G.M. Newbloom

10:10 Intermission.

10:25 711. Generation of well- defined electrophilic surface sites on sulfated zirconium oxide. M.P. Conley

10:45 712. Structural evolution of transition metal trisulfide electrode materials. V. Doan-Nguyen

11:05 713. New look at an old compound: X-ray photocrystallography studies of potassium ferrioxalate upon photolysis in the solid state. M. Nava, M. Gonzalez, E.J. Johnson, D.G. Nocera

11:25 714. Storing solar energy: Photochemical oxygen capture and thermal release. T. McCormick, L. Lutkus

11:45 715. KBaTeBiO6: Lead-free, inorganic double-perovskite semiconductor for photovoltaic applications. A.S. Thind, S. Kavadiya, M. Kouhnavard, R. Wheelus, S.B. Cho, L. Lin, A.Y. Borisevich, G. Pilania, P. Biswas, R. Mishra

Marriott Marquis San Diego

Section D

San Diego Ballroom Salon C
Marina

Nanoscience

B. G. Trewyn, Organizer

8:30 716. Prussian blue analogues for templated nanoparticle growth. E.T. Nguyen, D.A. Hardy, G.F. Strouse

8:50 717. Probing the electronic states of small metallic nanoparticles using conduction electron spin resonance. S.S. Cruz, B. Lear

9:10 718. Electrolyte-induced conformational change of alkanethiolate ligands on gold nanoparticles in organic solutions. V. Tanygin, B. Lear

9:30 719. Bottom-up design of metal oxide and peroxide nanoclusters using neural networks. P. Miro

9:50 720. Carbon capture with MgO(111). R.M. Richards

10:10 721. STEM-in-SEM methods for 2D material defect and reliability studies. E. Mansfield, J.D. Holm

10:30 722. Active plasmonics based devices using metal oxide nanocrystals: Fundamentals and applications. A. Agrawal, D.J. Milliron

Section E

Marriott Marquis San Diego Marina
Santa Rosa

Solid-State Inorganic Chemistry

C. G. Lugmair, V. Poltavets, Organizers
R. Compton, T. Ortner, Presiding

8:30 723. Vacuum transport of transition metal-doped ZnSe fiber lasers. A. Hendrickson, J. Krug, C.J. Mathewson, M. Coco, S.C. Aro, S. McDaniel, P. Sazio, J. Mauro, G. Cook, V. Gopalan, J.V. Badding

8:50 724. New methods for measuring absolute optical constants using loose powders: Implementation, validation, and renewable energy applications. P. Khalifah, T. Glotch

9:10 725. Tuning the photoluminescence by controlling the oxidation states of dopants. R. Gautier

9:30 726. New additions to the cesium lithium chloride system: Cs3Li2Cl5 and the hydrated Cs3LiCl4 * 4H2O. T. Ortner, J.P. Scheifers, Y. Zhang, A. Iyer, J. Flores, B. Fokwa

9:50 727. Dimensional reduction of halide double perovskites. B. Connor, L. Leppert, M.D. Smith, J. Neaton, H. Karunadasa

10:10 728. Redox properties of dysprosium 3+/4+ in barium zirconate. J.R. O’Brien, S. Ricote, L. Krishna

10:30 Intermission.

10:45 729. Structural and physical properties of CaLaMReO6. F. Yuan, C.M. Thompson

11:05 730. Geometrically frustrated magnetism in transition metal borides. A. Iyer, Y. Zhang, B. Fokwa

11:25 731. Varying the fermi level in gadolinium transition-metal aluminides. G. Agbeworvi, C. Thompson

11:45 732. Topotactic transformations of heterolayered borides. L. Alameda, R.E. Schaak 12:00 733. First-principles study of phase stabilities in Al1-xFexOOH and Al1-xCrxOOH metal oxyhydroxides. D. Pope, A.E. Clark, M. Prange

12:15 734. Manipulating magnetic properties via chemical variations in TlFe3Te3. R. Compton, C.M. Thompson

Section F

Marriott Marquis San Diego Marina
Marina Ballroom Salon E Organometallic Chemistry: Catalysis – Late Transition Metals

N. S. Radu, Organizer
M. A. Bowring, Presiding

8:30 735. Mechanistic insights of the direct arylation of arylhalides: Density functional theory study. R. Wei, P. Miro

8:50 736. Modeling the reactivity of alkanes toward organometallic electrophiles. P.J. Perez, A. Caballero, G. Asensio, M. Etienne, F. Maseras, A. Olmos, R. Gava, M. Besora, K. Jacobs

9:10 737. Thermodynamic hydricity as a tool for designing catalysts for hydrogenation of ketones and esters. E.S. Wiedner, B. Neisen, J.C. Linehan, A.M. Appel

9:30 738. Highly active ruthenium metathesis catalysts at low temperatures: Unprecedented ring- opening metathesis polymerization of cyclopentadiene. S. Hong

9:50 739. Robust Re(V) alkylidyne catalysts for alkyne metathesis reactions. M. Cui, W. Bai, H. Sung, I. Williams, Z. Lin, G. Jia

10:10 740. Strongly σ-donating ligands with pendant bases for water oxidation catalysis. A.G. Nash, B.D. Vincenzini, C.J. Breyer, B.E. Silva, D.B. Grotjahn 10:30 741. Large isotope effects in organometallic reactions. M.A. Bowring, P.T. Truong, E.D. Douma, M.P. Ahmad, Z. Mathe, J. Tsang

10:50 742. High variance of metal oxidation states in nickel catalysis. A. de Aguirre, I. Funes-Ardoiz, F. Maseras

11:10 743. Reversible CO2/formate conversion by a homogeneous platinum electrocatalyst. D.W. Cunningham, J.Y. Yang

Section G

Marriott Marquis San Diego Marina
Marina Ballroom Salon G

Main Group Chemistry

T. Hudnall, Organizer
F. Jaekle, E. Lee, Presiding

8:30 744. Reactive phosphenium cations. R. Dobrovetsky

8:50 745. N-heterocyclic carbene- functionalized ferrocenes. E. Lee

9:10 746. Lewis pair functionalization of polycyclic aromatic hydrocarbons. K. Liu, M. Vanga, R. Lalancette, F. Jaekle 9:30 747. Lewis adduct formation of sulfones, sulfonate, and sulfate esters with arsenic and antimony pentafluoride. T.H. Saal, K.O. Christe, R.M. Haiges

9:50 Intermission.

10:00 748. C6F5B-Binolate: Synthesis, structure, Lewis acid– base chemistry and catalytic activity. S. Garg, C. Krempner 10:20 749. Guanidine-based intramolecular frustrated Lewis pairs (FLPs): Synthesis, structure and small molecule activation. C. Manankandayalage, C. Krempner 10:40 750. Reductive elimination at a carbene center. D.R. Tolentino, S. Neale, C. Isaac, S. Macgregor, M.K. Whittlesey, R. Jazzar, G. Bertrand

11:00 751. Carbones and catalysis. T. Ong